An Alternative Synthesis of a Sex Pheromone of the Dry Bean Beetle Callosobruchus Analis
Russian chemical bulletin(1999)
摘要
A formal total synthesis of 3-methylhept-2(Z)-enoic acid, a sex pheromone of the dry bean beetleCallosobruchus analis, was performed on the basis of a highly stereoselective version of the Peterson olefination of ketones developed previously by the authors.
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关键词
stereoselective version of the Peterson olefination of ketones,insect pheromones,3-methylhept-2(Z)-enoic acid,3-phenylthiohexan-2-one,methyl andtert-butyl 3-methyl-4-phenylthiohept-2(Z)- and-2(E)-enoate,3-methyl-4-phenylthiohept-2(Z)- and-2(E)-enols
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