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Phase equilibria during crystallization of melts in the uranium oxide-iron oxide system in air

Yu. B. Petrov,Yu. P. Udalov,J. Subrt,S. Bakardjieva,P. Sazavsky,M. Kiselova,P. Selucky,P. Bezdicka,C. Journeau,P. Piluso

Glass Physics and Chemistry（2009）

Cited 13|Views18
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Abstract
The uranium oxide-iron oxide system is investigated. It is revealed that, upon both quenching and slow cooling of samples after their melting in air, the solid phase contains five crystalline phases, such as the oxide of quadruply charged uranium UO 2 , the mixed oxide UO 2.66 (U 3 O 8 ), hematite FeO 1.5 (Fe 2 O 3 ), magnetite Fe 1.33 (Fe 3 O 4 ), and the binary compound Fe 2+ U 6+ O 4 .
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Key words
Uranium,Iron Oxide,Glass Physic,Uranium Oxide,Severe Accident
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