Chrome Extension
WeChat Mini Program
Use on ChatGLM
VIPCreated with Sketch.

Ring Expansion/Homologation−Aldehyde Condensation Cascade Usingtert-Trihalomethylcarbinols

J. R. Falck,Anyu He,L. Manmohan Reddy,Abhijit Kundu,Deb K. Barma,A. Bandyopadhyay,Sukanta Kamila,Radha Akella,Romain Bejot,Charles Mioskowski

ORGANIC LETTERS（2006）

Cited 31|Views20
No score
Abstract
Treatment of cyclic tert-trihalomethylcarbinols with CrCl2 in THF/HMPA in the presence of aryl or aliphatic aldehydes initiates a cascade sequence of one carbon ring expansion-olefination affording conjugated exocyclic ketones. Acyclic tert-trihalomethylcarbinols undergo a comparable cascade of one carbon homologation-olefination.
More
Translated text
Key words
methanol
AI Read Science
Must-Reading Tree
Example
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined