1-Aminocyclopentanecarboxamide
Acta Crystallographica Section E-structure Reports Online(2004)
摘要
Crystals of the title compound, C6H12N2O, were obtained from the reduction–hydrolysis reaction of 1-amino-1-cyclopentanecarbonitrile oxalate and the structure was determined in the monoclinic space group C2/c. There are two independent molecules in the asymmetric unit and these assume different conformations. In the two cyclopentane rings, the minimum C—C bond length is 1.456 (3) A and the maximum is 1.531 (3) A. The weighted mean C—C bond length [1.483 (9) A] of the two cyclopentane rings is obviously shortened in comparison with the average literature value [1.543 (18) A] for a cyclopentane C—C bond. Hydrogen bonds of the N—H⋯O, N—H⋯N and C—H⋯O types are the principal intermolecular interactions.
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