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Synthetic coordination chemistry of transition metal ions and ligand design is central to our work with focus on new Fe(II) spin equilibria systems using pyridyl/pyrazole/imidazole-containing chelating ligands, stabilization of ligands, stabilization of high-valent iron, manganese, and nickel complexes and stabilization of ligand cation-radical complexes of deprotonated pyridine/pyrazine amide ligands, magneto-structural coorelations, design of anion receptors, and bioinorganic synthetic model complexes of metalloenzyme active sites (dioxygen activation, water oxidation, hydrolysis of substrates, and metal–coordinated phenoxyl radical complexes) using tailor-made ligands, and half-sandwich organometallic molecules. We also have interest in coordinaton polymers. Research covers extensive synthesis, molecular structural (X-ray crystallography), and electronic structural (magnetic, spectroscopic, and DFT calculations) characterization, and investigation of reactivity (chemical and redox).
Synthetic coordination chemistry of transition metal ions and ligand design is central to our work with focus on new Fe(II) spin equilibria systems using pyridyl/pyrazole/imidazole-containing chelating ligands, stabilization of ligands, stabilization of high-valent iron, manganese, and nickel complexes and stabilization of ligand cation-radical complexes of deprotonated pyridine/pyrazine amide ligands, magneto-structural coorelations, design of anion receptors, and bioinorganic synthetic model complexes of metalloenzyme active sites (dioxygen activation, water oxidation, hydrolysis of substrates, and metal–coordinated phenoxyl radical complexes) using tailor-made ligands, and half-sandwich organometallic molecules. We also have interest in coordinaton polymers. Research covers extensive synthesis, molecular structural (X-ray crystallography), and electronic structural (magnetic, spectroscopic, and DFT calculations) characterization, and investigation of reactivity (chemical and redox).
Research Interests
Papers共 232 篇Author StatisticsCo-AuthorSimilar Experts
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DALTON TRANSACTIONSno. 15 (2024): 6515-6519
Polyhedron (2023): 116652-116652
Polyhedron (2023): 116652
WORLD SCIENTIFIC eBookspp.81-122, (2023)
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FARADAY DISCUSSIONSno. 0 (2022): 129-142
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