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Research in the Widenhoefer group is directed toward the development and mechanistic analysis of new organotransition metal-catalyzed transformations for application in the synthesis of functionalized organic molecules. In particular, our group has a long-standing interest in the functionalization of C–C multiple bonds with carbon and heteroatom nucleophiles catalyzed by electrophilic late transition metal complexes, with a recent focus on the synthetic and mechanistic aspect of gold(I) pi-activation catalysis. Current areas of inquiry include the following: 1) Gold(I) and Pt(II)-catalyzed hydroamination of alkenes an allenes. 2) Gold(I)-catalyzed dehydrative amination of underivatized allylic alcohols. 3) Synthesis and study of cationic, two-coordinate gold pi-complexes. 4) Evaluating the role of bis(gold) complexes in gold pi-activation catalysis. More detailed descriptions of these research projects can be found at our group web page.
Research Interests
Papers共 271 篇Author StatisticsCo-AuthorSimilar Experts
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CHEMCATCHEMno. 5 (2024)
CHEMPLUSCHEMno. 6 (2024): e202300691-e202300691
ORGANOMETALLICSno. 15 (2023): 1918-1926
crossref(2022)
ORGANOMETALLICSno. 19 (2022): 2753-2763
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