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Bio
One goal of studies carried out in professor Mariano's research group is to develop novel synthetic methods and to apply them in concise routes for the preparation of several biomedically interesting targets. One methodology is based on the deceptively simple photocyclization reaction of pyridinium salts, which the Professor Mariano's laboratory has transformed into a potent methodology for the stereocontrolled synthesis of highly functionalized aminocyclopentene derivatives. The preparative potential of these photocyclization reactions is being probed in applications to stereochemically controlled syntheses of (1) the proteasome inhibitor (+)-lactacystin, (2) the unusually structured, cytotoxic marine alkaloid (-)-lepadiformine, and (3) the potent glycosidase inhibitor (+)-broussonetine G.
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Green Synthesis and Catalysisno. 1 (2021): 27-31
Green Synthesis and Catalysisno. 1 (2021): 27-31
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