基本信息
浏览量:0
![](https://originalfileserver.aminer.cn/sys/aminer/icon/show-trajectory.png)
个人简介
Research: For well over 40 years, my research was mainly concerned with elucidating the Mechanisms of Organic Chemical Reactions. I was especially interested in reactions involving highly reactive minority species, e.g. enols, enolates and enamines. My group's projects often entailed the study of transient intermediates through direct spectroscopic observation and/or from the analysis of reaction kinetics. We showed that the electrophilic bromination of many aromatic and heteroaromatic compounds in aqueous solution involves at least two steps, and one or more of these steps may be catalyzed by acids, bases, metal ions, and/or complexing agents. My last research was concerned with the effects of solvents or host-guest binding on organic reactivity. I was interested in Transition State Stabilization arising from solvent change or the binding of transition states to Catalysts (actual or potential) such as dendrimers, micelles and cyclodextrins ("nanobuckets"). In effect, our work delved into the origins of Supramolecular Catalysis. For more details click on one of the links below.
研究兴趣
论文共 155 篇作者统计合作学者相似作者
按年份排序按引用量排序主题筛选期刊级别筛选合作者筛选合作机构筛选
时间
引用量
主题
期刊级别
合作者
合作机构
CANADIAN JOURNAL OF CHEMISTRYno. 8 (2000): 1100-1108
加载更多
作者统计
合作学者
合作机构
D-Core
- 合作者
- 学生
- 导师
数据免责声明
页面数据均来自互联网公开来源、合作出版商和通过AI技术自动分析结果,我们不对页面数据的有效性、准确性、正确性、可靠性、完整性和及时性做出任何承诺和保证。若有疑问,可以通过电子邮件方式联系我们:report@aminer.cn