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Bartlett's main specialty was the chemistry of fluorine and of compounds containing fluorine. In 1962, Bartlett prepared the first noble gas compound, xenon hexafluoroplatinate, Xe+[PtF6]−. This contradicted established models of the nature of valency, as it was believed that all noble gases were entirely inert to chemical combination. He subsequently produced and reproduced several other fluorides of xenon: XeF2, XeF4, and XeF6. By exploiting the solvent and basic properties of XeF6, he was able to prepare the first quinquevalent gold compound, Xe2F11+AuF6−.
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ChemInformno. 26 (2010)
Inorganic Synthesespp.10-11, (2007)
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