基本信息
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The research program of Prof. Limbach was focused on the design and the study by NMR spectroscopy of the structure and dynamics of isotopically labeled molecular model systems for proton and hydride transfer.
The range between small organic molecules embedded in liquids, solids and surfaces, modified enzymes, oligonucleotides and transition metal hydrides as well as transition metal nanoparticles was covered. For that purpoes, variable temperature liquid and solid state NMR spectroscopy were applied.
The aim was to measure kinetic, equilibrium and geometric isotope, tunneling, solvent and surface effects of hydrogen transfer in high- and low-barrier hydrogen bonds and in the coordination sphere of transition metal catalysts, and to model the results theoretically.
The range between small organic molecules embedded in liquids, solids and surfaces, modified enzymes, oligonucleotides and transition metal hydrides as well as transition metal nanoparticles was covered. For that purpoes, variable temperature liquid and solid state NMR spectroscopy were applied.
The aim was to measure kinetic, equilibrium and geometric isotope, tunneling, solvent and surface effects of hydrogen transfer in high- and low-barrier hydrogen bonds and in the coordination sphere of transition metal catalysts, and to model the results theoretically.
Research Interests
Papers共 410 篇Author StatisticsCo-AuthorSimilar Experts
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Hans-Heinrich Limbach, Simone Baumgärtner, Roland Franke,Ferdinand Männle,Gerd Scherer, Gleb S. Denisov
Moleculesno. 14 (2021): 4373
Hans-Heinrich Limbach, Simone Baumgärtner, Roland Franke,Ferdinand Männle,Gerd Scherer,Gleb S Denisov
Solidsno. 2 (2021): 139-154
Verónica Torres Barthelemy,Natalia Pérez-Hernández,Ilya G. Shenderovich,Peter M. Tolstoy,Gleb S. Denisov,Hans-Heinrich Limbach
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