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This research program is exploring and developing new areas of chemical reactivity and catalysis by controlling the movement of electrons. An obvious example is electrocatalysis, which is a central theme of our studies, but in a broader sense all chemical behavior may be viewed as the movement of electrons. This includes the oxidation and reduction processes of metalloenzymes in biology, the selective making and breaking of bonds in industrial catalysis, the transport of electrons in molecular wires, and the interactions of molecules with light. Chemical reactivity and catalysis depend on mechanisms that move electrons from existing bonds in starting materials to new bonds in desired products. Movement of electrons in materials is important to electrical conductivity and optical properties for technological applications. In biology, electron transfer involving active metal sites is central to many life processes. This research provides fundamental information for understanding all of these processes - the clues for solving the many mysteries of electron behavior in chemistry.
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Journal of the American Chemical Societyno. 25 (2023): 13912-13919
Nathan Bedard, Addison G. Coen, Scott Pekarske, Andrew Sennett,Garrett J. Davis, Timothy Chavez,Dennis L. Lichtenberger,Christopher Hulme
Tetrahedron Letters (2023): 154748-154748
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