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Bio
Benito Alcaide was born in Aldea del Rey (Ciudad Real, La Mancha, Spain), on April 29, 1950.
One of the major interests of Benito Alcaide over the years has been in the area of cycloaddition chemistry. The use of thermo or catalyzed ene reactions, Diels–Alder reactions, hetero Diels–Alder reactions, 1,3-dipolar cycloadditions of both nitrones and azomethine ylides, as well as [2+2] cycloaddition reactions gave rise to a variety of diversely functionalized 2-azetidinones. Benito also studied organocatalysis, which has emerged as a new and powerful tool in chemical synthesis. During recent years the use of transition metals in organic synthesis has also been a focus of his research. One of the most important of all these achievements has been the discovery of a practical ruthenium-catalyzed cleavage of the allyl protecting group in amines, amides, lactams, imides, and related compounds. Particularly remarkable are the studies on the controlled chemo-, regio-, and stereoselective cyclizations of allenes. For example, he developed metal-catalyzed domino cyclizations of •-allenols followed by a coupling reaction leading to functionalized dihydrofuran derivatives.
One of the major interests of Benito Alcaide over the years has been in the area of cycloaddition chemistry. The use of thermo or catalyzed ene reactions, Diels–Alder reactions, hetero Diels–Alder reactions, 1,3-dipolar cycloadditions of both nitrones and azomethine ylides, as well as [2+2] cycloaddition reactions gave rise to a variety of diversely functionalized 2-azetidinones. Benito also studied organocatalysis, which has emerged as a new and powerful tool in chemical synthesis. During recent years the use of transition metals in organic synthesis has also been a focus of his research. One of the most important of all these achievements has been the discovery of a practical ruthenium-catalyzed cleavage of the allyl protecting group in amines, amides, lactams, imides, and related compounds. Particularly remarkable are the studies on the controlled chemo-, regio-, and stereoselective cyclizations of allenes. For example, he developed metal-catalyzed domino cyclizations of •-allenols followed by a coupling reaction leading to functionalized dihydrofuran derivatives.
Research Interests
Papers共 522 篇Author StatisticsCo-AuthorSimilar Experts
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Atropisomerism and Axial Chiralitypp.541-609, (2019)
ADVANCES IN TRANSITION-METAL MEDIATED HETEROCYCLIC SYNTHESIS (2018)
Alcaide Benito,Almendros Pedro, Aragoncillo Abanades Cristina, Busto Eduardo,G Lopez-Calixto Carmen,Liras Torrente Marta, A de la Pena O’Shea Victor, Garcia-Sanchez Alba, V Stone Hannah
Chemistry - European Journalno. 30 (2018): 7620-7625
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