基本信息
浏览量:112
职业迁徙
个人简介
Research Interests
Recent advances in the instrumentation for small molecule X-ray crystallography have made it possible to complete a full structural characterization of a new material in less time, at less expense and with far less ambiguity than any other characterizational method currently available.
Prof. Rheingold's research explores ways of using X-ray crystallography to provide very rapid and accurate structural characterizations of new compounds in collaboration with members of this department and with several hundred chemists from about fifty other departments worldwide. He welcomes inquiries regarding the establishment of new collaborations, particularly in the areas of inorganic and organometallic chemistry.
His interest in crystallography arose from his research in the synthesis and properties of large cluster structures containing hybrid p-block and transition-metal atoms. These are often paramagnetic solids necessitating crystallographic characterization. A recent example is the di-cubane structure, {[(Cp*CrSe)3Se]2(µ6-As)}, shown below. It contains Cr in a non-integral oxidation state and it behaves ferromagnetically at low temperatures. Such hybrid clusters are of interest as precursors to new materials displaying thermoelectric and thermomagnetic properties. Simple tetrahedrane analogues such as [(CO)3CoAs3] are found to be excellent volatile precursors to skudderudite phases useful in high-temperature Seebach-effect applications. Both of these metal/p-block hybrid clusters was formed from p-block hetero- and homo-cyclic precursors; in the cases above: (CH3AsSe)3 and (CH3As)5.
研究兴趣
论文共 3200 篇作者统计合作学者相似作者
按年份排序按引用量排序主题筛选期刊级别筛选合作者筛选合作机构筛选
时间
引用量
主题
期刊级别
合作者
合作机构
Jorge A. Garduno, Andrew J. Sasser, Hannah J. Sexton, Russell P. Hughes,David S. Glueck,Arnold L. Rheingold
ORGANOMETALLICSno. 3 (2024): 381-394
Structural Chemistrypp.1-16, (2024)
Miranda P. Howard,Preston M. Miura-Akagi,Timothy W. Chapp, Yuri J.H. Ah-Tye, Tomoko Kitano, Daniel Y. Zhou, Landon G. Balkwill,Wesley Y. Yoshida,Amy L. Fuller,Glenn P.A. Yap,Arnold L. Rheingold,Gabriela L. Borosky,
Polyhedron (2024): 116905
Evan A Doud, James A R Tilden,Joseph W Treacy, Elaine Y Chao,Hayden R Montgomery, Grace E Kunkel, Eileen J Olivares, Nima Adhami,Tyler A Kerr,Yu Chen,Arnold L Rheingold,Joseph A Loo,
Journal of the American Chemical Society (2024)
Ryan M. Tipker,Russell P. Hughes,David S. Glueck, Heather A. Spinney, Michael A. Brammer,Arnold L. Rheingold
ORGANOMETALLICSno. 3 (2024): 427-431
ORGANOMETALLICSno. 13 (2023): 1448-1453
引用0浏览0引用
0
0
Lihua Liu,Daniel Mendoza-Espinosa, Mauricio Quiroz-Guzman,Arnold L. Rheingold,Tracy A. Hanna,Gobinda Saha,Liming Tang,Yanhui Chen,Megan Gilbert,Abhirup Dutta,Alexandru D. Asandei
加载更多
作者统计
合作学者
合作机构
D-Core
- 合作者
- 学生
- 导师
数据免责声明
页面数据均来自互联网公开来源、合作出版商和通过AI技术自动分析结果,我们不对页面数据的有效性、准确性、正确性、可靠性、完整性和及时性做出任何承诺和保证。若有疑问,可以通过电子邮件方式联系我们:report@aminer.cn