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个人简介
Research Interests:
• Enzymatic redox catalysis: Fundamental elements: electron transfer, proton transfer and coupling.
• Redox tuning: identification of hydrogen bonds, electrostatic and steric interactions by which proteins modulate
properties of redox centers and thereby the nature of reactivity (1-e vs. 2-e, vs. bifurcation), non-heme Fe & flavins.
• NMR shielding tensors as reporters of flavin electronics, their relation to reactivity and their manipulation by the
protein, via solid-state NMR in conjunction with high-level DFT calculations.
• Protein biophysics: coupling between protein dynamics and substrate (analog) binding.
• Dynamic nuclear polarization site-selective enhancements of NMR signals via radical states of bound cofactors.
• Enzyme-functionalized electrodes/membranes: remediation and enzymatic capture of chemical energy from waste
products, and conversion into electrical energy.
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Sharique Khan, Ahmadullah Ansari, Monica Brachi,Debarati Das, Wassim El Housseini, Shelley Minteer,Anne-Frances Miller
The Journal of biological chemistryno. 4 (2024): 107122-107122
Journal of Biological Chemistryno. 3 (2023): S331-S332
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EUROPEAN BIOPHYSICS JOURNAL WITH BIOPHYSICS LETTERSno. SUPPL 1 (2023): S183-S183
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Journal of Biological Chemistryno. 3 (2023): S319-S319
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JOURNAL OF BIOLOGICAL CHEMISTRYno. 3 (2023): S307-S308
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